I don't recommend Kalkwasser dosing without some fairly serious safeguards against overdosing. A single mechanical valve? Nope, not me. Simple ATO? with a 5g reservoir, on a tank with a total volume of 75 gallons or so... If it all dumps in, well, no big deal. Dump 5g of saturated kalk solution? You'll wipe out the tank. I'm fine with a simple mechanical ATO, with a LIMITED quantity of RO/DI, but for anything with a higher chance of killing the system, I want more.
Don't get me wrong... I like kalkwasser, and highly recommend it, if you've got a system that can be supported by it, it's an excellent way to go. But. You've _got_ to be safe about it.
My current ATO reservoir fill... RO/DI unit is plumbed through a solenoid, run by my controller. Solenoid is only open for a couple of hours, twice a week. My RO/DI won't produce much more than what I'm needing in that amount of time. When the solenoid is open, there is a float switch at the top of my ATO reservoir that will close it, if the water level reaches that level... which it should never do, since the outlet into the reservoir is on a float valve. Oh, and I have a cheap battery powered water alarm on the floor next to the reservoir.
So... I don't have to manually do anything, when the RO/DI unit kicks on, it needs to produce a couple of gallons of water at a time, so I'm avoiding the RO/DI 'creep' issue that people talk about, and, IF something goes wrong, I'd have to have a minimum of 2 devices fail before it would cause a problem, and even then, it's not really that bad of a problem.
From the reservoir to the sump, I'm using a Tunze ATO... It has an optical sensor, backup mechanical sensor, and a timer to limit the damage if both fail. I don't like to mix Kalkwassser in my ATO reservoir, mostly because it's hard on the pump... so I use an inline Kalk mixing device (Tunze 5074 Calc Dispenser), with an inline anti-back flow valve.
Complex? Perhaps... but it's quite safe, and other than inspecting the system weekly, I don't have to touch a thing.