If you're looking at the back compartment, it should be the surface skimmer compartment on the left, the water goes down under the baffle into the second chamber and goes over the baffle into the third chamber on the right (the one with the pump). Is that correct?
If so, you need more water. You don't have enough water and therefore the second chamber isn't filling enough to overflow into the third. As a result, you're only pulling from the third compartment. This is the compartment that you will monitor once the tank is filled enough and add RO water due to evaporation. Before you fill the evaporation, I would fill the tank up completely with enough saltwater for it to work.
I would check that your tank is low on total saltwater before you top off evaporation, otherwise you'll skew the salinity too much. Once the proper level is set, only add RO water with evaproation.