Did you shake the reagent before using it? Is it a new bottle of reagent? Are you making sure there are no bubbles, or fingerprints on the vial?
These are all known to throw the checker off.
I would also agree that with a salinity that low, there is absolutely 0 way to have an alkalinity that high without dosing it(there is not a single salt that mixes that high in alkalinity with that low of a salinity). On that same note, how did you buy the salt? Was it in a bag, box, or bucket? if the latter 2, settling can occur throwing parameters off.
Being that your calibrating your salinity with RO/DI tells me it's off. Close but probably higher then you think.