Most two-part calcium and alk supplements are designed so that dosing equal amounts will maintain the balance of ions in your system. You're basically adding calcium chloride (the calcium part) plus sodium carbonate or sodium bicarbonate (the alk part), so the calcium and the carbonate become available to your coral in the same ratio that they normally uptake from the water to build their skeletons, and the sodium and chloride just end up as salt.
Like
@BadPanda said there might be times when you need to raise either calcium or alk relative to the other, but once you reach target levels you should dose in equal amounts (assuming the supplements you are using were designed as a two-part system). There's a good article here by
@Randy Holmes-Farley about getting calcium and alkalinity in line with each other (I think it's still a valid URL but for some reason seems not to be working right now):
https://www.advancedaquarist.com/2002/11/chemistry