Many salt mixes have excess calcium, requiring imbalanced dosing. Alkalinity can also be depleted in ways other than calcification, such as rising nitrate.
So there is no inherent reason one must dose equally, and further, not all two parts are designed for 1:1 dosing, even some that claim to be (such as Seachem Reef Fusion).
Any two part that is designed for 1:1 dosing should be started at 1:1 dosing based on alkalinity measurement.
Then, over a period of weeks, the calcium can be adjusted up or down as needed. Not daily. There is way too much short term noise in calcium testing to rely on short periods to determine the calcium doses for maintenance.