3 Tanks: mysterious pH dive

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NanJ

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We had a very mysterious pH drop in 3 tanks Friday night that I though interesting enough to post and see if anyone has ideas to explain what happened.

Our set up: 300 gallon DT on main floor, 100 gallon sump in walk-out/finished basement 'fish room' along with 55 gallon fish QT and 20 gallon coral QT. The systems have been running for one year. There are just the two of us living in the house along with two Golden Retrievers. Our house is one year old, fairly large and reasonably tight. We are in South Carolina so temperatures are pretty mild.

What happened: Overnight Friday night the pH dropped 0.3-0.4 on all three tanks. Since the tanks are separate, we had to assume it was environmental, i.e. a CO2 issue. When we got up on Saturday and saw the issues we turned on the furnace fan to run continuously, opened a couple of windows and put a big fan in the fish room to circulate air. Over the day, the pH climbed back close to normal on all three tanks. These are images from our Apex system for each tank.

Display Tank / Coral QT / Fish QT
DT pH.jpg
Coral QT pH.jpg
Fish QT pH.jpg


We are completely flummoxed as to what could have caused this We have a heat pump/propane dual fuel heating system and keep the basement thermostat at 65. The propane furnace doesn't kick in unless the outdoor temperature is less than 40. When the pH drop happened, the outdoor temp only got to 41. We have a propane tankless water heater (wall-mounted in the fish room) which only burns propane when in use - and it wasn't in use overnight. No fireplace in the house. The oven was on Friday from about 6-7 pm at 550 degrees to cook pizza but it is an electric oven - and I cook pizza at this temp almost every week.

Any ideas to explain this are much appreciated. I assume if it happens again, we will have to think about having some sort of professional evaluation of our home's ventilation.
 
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Any large number of people over?

might just be a measurement issue of some sort. pH meters in aquarium controllers seem prone to odd issues.

It might indicate a failure of the heat transfer part of the furnace, letting CO2 into the home. If it seems to happen again, I’d be sure to have carbon monoxide detectors working in case that is it.
 
Randy, thanks for taking a look. This one may go down as an unsolvable mystery.

No, just the two of us here for the several days prior.

I did think of squirrelly pH meters but all three? Then I thought of something odd in Apex software but our maintenance person from the LFS store did not see any Apex issues with other tanks he monitors.

The furnace could be the issue although I don't think the propane part of it ran overnight, just the outdoor heat pump. Imagine the conversation with the HVAC people when I try to explain why we want it checked: "The pH in our aquariums took a nose dive which could indicate a carbon dioxide issue. Can you take a look?" Imagine I'd get that blink, blink look.

We do have CO monitors and assume they work correctly - scary thought!
 

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