Jeffery, I know this an old response and you've probably realized that 8.2 to 8.4 is the perfect pH range for your tank. But you are changing things in your system by running such a long line through your skimmer, while also scrubbing out CO2... Explained below but just concepts are explained so anyone could decide what to do here. However my advice is to choose one over the other, but not both. I like the CO2 scrubber, but that's just me.
I have used CO2 scrubbers for years with great effect on pH. I have run a line to the outside as well, but there was definitely a change in the dynamics of my skimmer at the time (Reef Octo initially, now Deltec). So I added a Luft pump to the outside line intake so it could push air in under pressure (since that's the point of a Luft pump) and that changed skimmer dynamics as well. I'm sure I could have adjusted the skimmer pump to deal with the higher pressure from the Luft, however I didn't fool with that.
Either way, I would recommend pressurizing a long run of airline, or increasing the diameter of hosing to at least 1/2 " as
@Downbeach already stated, and additionally I would add the super flexible thick silicone tubing like the kind used on return pumps for silencing/dampening vibrations, link here to
BRS. No thinner than 1/2" though. Skimmers are pretty precisely designed now, pumps matched pretty exactly to skimmer body, height, circumference, neck length, type of impeller used etc., so any change in airflow dynamics has a resultant effect on the entire skimmer, whether we notice or not. Each kind of skimmer as well have skimmate profiles that remove specific amounts and types of DOC's, and as a result skimmate profiles trend downwards (in terms of ability to remove very specific percentages of DOC's) with airflow dynamics changes that are made to it.
There is an upside to outside air over an air scrubber though, meaning CO2 is used by zooxanthellae in some instances for photosynthesis, while other corals can use bicarb directly (reference article written by
Dana Riddle here). In any case, scrubbing CO2 out of a tank may result in slower coral growth rates or create the need to raise levels of alkalinity or bicarb to much higher levels for direct use. But that is another thread altogether.
Last point on this topic I promise. It is just as important to recognize the importance, or not, of the source of dissolved oxygen levels in our tanks. Outside air will not cause an appreciable increase of dissolved O2 in our tanks, although outside air does cause a very appreciable decrease in CO2, compared to air internal to the house. This varying difference in dissolved O2 vs. CO2 levels is simply proportionate to the concentrations of the two gasses in atmospheric air; 20.95% vs. 0.04%, respectively. In essence by using outside air, we don't change the amount of dissolved O2 in tank, but we do appreciably change the amount of CO2. O2 inside our homes doesn't drop by enough to keep our skimmers from saturating our tanks with dissolved O2. Another thread topic though.
Just wanted to drop in and thank
@jsker for the post/article!
I run CO2 scrubbers to keep skimmer function similar to the way it was designed, and keep some windows open to allow fresh air in as well while switching the CO2 scrubber either off or allowing dual intakes into one line so not to strip my tank of CO2 needed for proper coral photosynthesis and growth. Hope that long post didn't bore you all to sleep.