Alk Bouncing Back

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Before I post my question I'll point out that I have used search and read many posts on this issue but none seem to have an answer that makes sense in my tank.

Several weeks ago I noticed (for second or third time over a few months) that my Alk was increasing despite no change in my AFR dosing from months prior. The first spike I attributed to either reduced lighting and thus reduced uptake without a commensurate reduction in AFR or to an overdose of lime paste I used to kill a few aiptaisia (very small amount so I doubt this was it but I had no other explanation). More recently though my lights have been ramping up, so that wouldn't be the cause and it got me wondering why my Alk consumption seemed to be dropping therefore making my Alk rise as result of the dosing.

To validate my reading I decided to completely stop AFR dosing. After a few days to account for the AFR lag I was still seeing no drop in Alk. That's when I started doing my google searches. I can clearly see coral growth (leptoseris, multiple favites, chalice) so there should be demand yet my Alk is going up, rather than down. Ca has been slowly depleting, around 5 ppm per week if I remember right (no log in front of me). My searches on here eluded to nitrogen dosing or certain supplements/food raising alkalinity so I stopped any of those. I was using Reef Energy AB+ and very infrequently neo Nitro/Phos if those numbers were dropping and feeding wasn't bringing them up. My tank is 6 months old, started from dry rock, no hard sand chunks that I've noticed (4 super nassarius are keeping stirred to some degree). Also no major drops in NO3.

To bring my Alk down and further validate what I was seeing I performed small water changes with low Alk water to bring my Alk from 9.9 to around 9.6. All Alk measurements (salifert) have been dead on with what I've calculated with math. Every time I've reduced the Alk with a water change within two days it's right back to around 9.9-10. I've done this three times, and each time the same. The first time I figured there could be test error but after three times every reading is coming out the same. These are freshly mixed batches of water, not the same one partially used. My tank reads 9.9-10, new water reads 6 (2gal) or 4.5 (1gal), resulting tank Alk 9.5-9.6. About two days later Alk test is back to 9.9-10. I haven't let it go for a lot longer to see if it continues rising but for just a couple days it seems to stall at that 9.9-10 mark.

What gives? No dosing. Feeding fish Xtreme pellets and Rod's food. Purposely reducing Alk via H2O change. Coral is growing. Alk still rising.

Could there be a lag in alkalinity with my new salt water? After mixing and at time of change it read the 4.5 or 6 but could that be rising later and by the time it does it's in the tank?

Been monitoring this phenomenon for about two weeks now so below params are just a point in time:

Total vol: 20 gallons
SG: 1.026
Temp: 78.5
Alk: 9.9
Ca: 430
Mg: 1350ish (no log in front of me)
NO3: 5-10 (with the exception of a drop to 0 a few weeks ago it's been in this range for the entire time I've had livestock)
PO4: .05-.07
No skimmer
No reactors or any other "gadgets"

I know lots of people keep their tank at 10 with no issue but each time I've noticed my coral looking a little annoyed it's been when the Alk is higher. Could just be lower nutrients combined with the higher Alk. I do not need a specific number but I'd really love to not worry about my Alk continually rising if I do nothing and don't want to be a slave to daily Alk testing.
 
Alk can rise without dosing for the following reasons:

1. Rock and sand can very slowly dissolve. This is often noted in long time reefers aquaria where they sometimes add more sand to replace loses. Larry Jackson was the first person I saw 20+ years ago who noted this effect.

2. Nitrate dosing boosts alk, as does declining nitrate. Each 50 ppm dosed or declined adds 4.5 dKH.

3. Top off water can contain alk if it is tap water.

If you have ongoing alk boosts and very low demand to offset it, then water changes with a low alk mix (you can drop alk to zero in new salt water) will reduce that issue.
 
Randy,
Thanks for the reply. I saw many of these in the other posts but perhaps I'm missing something in the equation.
Alk can rise without dosing for the following reasons:

1. Rock and sand can very slowly dissolve. This is often noted in long time reefers aquaria where they sometimes add more sand to replace loses. Larry Jackson was the first person I saw 20+ years ago who noted this effect.
With a 6 month old tank I assume this is not the case, especially since I see such a rapid rebound. Safe assumption?
2. Nitrate dosing boosts alk, as does declining nitrate. Each 50 ppm dosed or declined adds 4.5 dKH.
This has really got me thinking. I know physically removed nitrate doesn't change Alk but metabolized (?) nitrate does. If my nitrates are remaining steady, but I am physically removing some through a water change that means I have a net positive input....through food if I'm not actually dosing it. Does food introduced nitrate have the same effect as dosed nitrate? If adding, and then consumed nitrate both raise Alk wouldn't all tanks constantly rise? Is there any nitrate mechanism that reduces alk or is it just the coral consumption that balances out that rise?
3. Top off water can contain alk if it is tap water.
Use RO/DI and have tested it at 0 dKH
If you have ongoing alk boosts and very low demand to offset it, then water changes with a low alk mix (you can drop alk to zero in new salt water) will reduce that issue.
Exactly what I have been doing only to be back to square one in a couple days. How much negative change can I safely make with one change? I have been limiting it to less than .5 dKH. Can I go bigger faster?

Thanks!
 
I'd stop dosing AFR and continue monitoring ALK/CAL/MAG and dosing individually until target ranges are met, then start up AFR slowly again and see how the numbers respond. Until then, water changes to slowly bring it down.
 
If it stalls at 9,10,11, whatever, that’s fine, stability is what your looking for not level.
All hobby grade test have a margin of error.
When stops rising (with the exception of beyond 12) it’s pinned, leave it alone and just keep a weekly watch.
 
I'd stop dosing AFR and continue monitoring ALK/CAL/MAG and dosing individually until target ranges are met, then start up AFR slowly again and see how the numbers respond. Until then, water changes to slowly bring it down.
I haven’t dosed anything in 5-6 weeks. That’s why this is particularly puzzling. No dosing, changing water every 3 days or so to bring it down about .5dKH but then it goes right back where it was.

On a good note, today my alkalinity was either the same or only .1 higher than 3 days ago. That is less of a rise than previously so either the bounce it’s slowing down or 10.2ish is where it want to level out.
 
If it stalls at 9,10,11, whatever, that’s fine, stability is what your looking for not level.
All hobby grade test have a margin of error.
When stops rising (with the exception of beyond 12) it’s pinned, leave it alone and just keep a weekly watch.
That what I was hoping to do but each time it would rise above 10 I could tell because my defcon cyphastrea would start losing some tissue.

I’m now thinking maybe it was coincidental because this past week it’s hit 10.2 twice and the cyphastrea is fine.
 

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