Alk/PH question

cope413

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I've looked around and can't seem to find an answer to my question, so if this has been covered elsewhere, a link to a thread would be excellent.

I totally understand if this is TL;DR material, but I really loved how maintenance free my tank was and it's not that way currently...

I've had a pretty stable system for about 2 years. I got an Apex in January. Prior to that I'd checked pH very infrequently (maybe every 2-3 months) and it was usually 8-8.1 on a pinpoint checker.

Until September, my pH was 8.0-8.18, and the average was ~8.09 according to the Apex data.

I dose with Randy's 2-part (BRS). 40g display, 30g sump. I was dosing ~26ml each per day (my dosers are close to 1.1ml/minute, and they run 24 minutes/day)
I test alk and cal weekly - alk was around 8.4, cal is ~410 (red sea kit)

I've never cared much about pH - definitely never chased numbers. Based on what I've read from Randy and others, as long as your system is stable and somewhere between 7.8 and 8.5 you're probably just fine.

About 3 months ago I started getting some alerts on my Apex that pH was >8.5 in the middle of day (highest I saw was 8.69). I had been dosing alk/cal 1 minute per hour, 30 minutes apart. (Alk for 1 minute at 8am, Cal for 1 minute at 8:30am, etc)
I programmed alk doser to shut off if pH was higher than 8.5, but I was still 8.5+ for 4-5 hours/day.

So, for the sake of not having a pH higher than what seems to be generally recommended, I adjusted to only dose the alk after the lights went out. I run an 11-hour lighting schedule (7:30-6:30), so i adjusted to dose alk for a minute 48 seconds every hour while lights were off.
I also run a reverse light schedule on my sump which has a grapefruit sized ball of chaeto and 20-30lbs of live rock in it.

This prevented the pH from exceeding 8.5 for about a month, but my pH average started slowly creeping up.

3 weeks ago I had to cut my alk dosing in half to keep from exceeding 8.5 during the day. I also changed the dosing schedule to 13 minutes at 3am when pH bottomed out at night. When I kept it at even doses every hour with lights out, it had virtually no drop at night and would then still peak over 8.6 during the day.

Attached a picture showing the past week of temp and pH.
PH-Temp.jpg

If you look at the trend in the graph, you can see that starting the 24th, each days' peak pH is slightly higher than the previous until the 28th when I did a water change. It goes up about .03/day.
(Big drop in temp was during a glass cleaning when I removed the temp probe from the water for a few minutes)

I checked my pH probe against calibration fluid it seems to be accurate. My pinpoint pH checker matches the readings too.

I'm now doing weekly water changes to compensate for the alk drop.

I've added a few small frags in the past month or so - but nothing I can think of has changed in quite a while.

Any ideas as to what's going on?

Should I revert back to my normal alk dosing and see if the pH continues to climb or if it stays around 8.6-8.65?

Is that or could that be harmful to anything?

Am I just totally missing something?

Here's other potentially relevant information/parameters

1.025sg
Instant Ocean Salt
I had an airstone in my sump which has now been turned off.
I have a skimmer and a reactor with high capacity GFO.
Purigen and carbon in bags. No filter socks.
0.0 ammonia and nitrites
Nitrates are undetectable with API test kit
Phosphates are either 0.0 or 0.3 on hanna checker
Mag is ~1450


Also filed under "if it matters", I have a large-ish squamosa, a BTA, and various LPS and zoos. 4 fish and assorted inverts.
Everything is doing fine and growing, with the exception of the BTA. Doesn't look bad, but it hasn't grown at all since I got it in February.

I'd love to hear that I'm completely over thinking this, but it seems very odd and I didn't want to risk losing anything. I figured I would isolate the issue or cause, but it's been 2+ months and I'm at a loss.

Input is much appreciated.
 
Maybe recalibrate your Ph probe to verify it's accuracy. I try to keep my Alk around 8.0 dkh. I run into to low of a Ph in the winter do to higher CO2 levels in the closed house. I assume you are not running ozone. I wish I could be of more help. There are short term fixes but I wouldn't recommend continous usage.
 
What is your alkalinity? I saw a big spike in my ph and tested my alk to find out it was 12dkh. I don't know the science but there is a correlation between high pH and high alk.
 
Maybe look at trying the low pH version of the diy alk. I think it is plain baking soda, not soda ash.

Let me find a link

http://www.reefkeeping.com/issues/2006-02/rhf/#2

So look at recipe #2, it is for tanks running above 8.3

Sorry I don't have an answer for why you are running high.. But at least this recipe would let you keep you alk up

How are you checking salinity? And has it been calibrated?
 
Last edited:
pH probe was checked against Randys DIY solution as well as a pouch of Apex calibration fluid. My pinpoint pH probe matches the same reading as the apex probe.

I was keeping alk around 8.4. It drops to 7 in about a week with my current dosing schedule.

I check my sg with refractometer. I have calibration fluid for it. I have apex Salinity probe and it reads about the same as meter. I calibrated it about 3 months ago. I don't rely on it though, it crept on me when I first got it, and salinity got to 1.03 before I noticed.
 
I would get some new pH calibration fluid. Old fluids (especially pH 10) tends to lower in pH as CO2 enters it, making readings after calibrating with it seem higher than they are. Rarely do tanks using a two part get above pH 8.5.

That said, switching to baking soda will certainly lower the pH relative to using sodium carbonate. Also, if the pH really is high (8.5) when alk is normal, more aeration will definitely bring it down.

This has more:

High pH: Causes and Cures by Randy Holmes-Farley - Reefkeeping.com
http://reefkeeping.com/issues/2005-03/rhf/index.htm

and this explains the difference between the types of additives and the pH:

Chemistry And The Aquarium: The Relationship Between Alkalinity And pH ? Advanced Aquarist | Aquarist Magazine and Blog
http://www.advancedaquarist.com/issues/may2002/chem.htm
 
Randy,

I had a fresh calibration fluid pouch from Apex - one time use, and I made a DIY fluid with nitric acid per your article. Both reported properly. My pinpoint pH probe was a little off, but the apex probe was dead nuts.

I added an airstone to my sump in January after reading one of these articles, but for my tank, it seemed to keep the pH higher than without it. I don't have the exact numbers, but IIRC, my diurnal swings were ~.15-.2 without the aeration. With the airstone they were about half that.

I turned off the airstone a few weeks ago because it seemed to be keeping the pH higher when the lights were off.

Re-reading the articles, it seems that this is opposite of expected outcome.

Improper correlation/causation on my part?

If a switch to baking soda is all that's needed to fix it, then that's easy. I just don't quite understand what's happening and what changed to cause it.
 
Randy,

I had a fresh calibration fluid pouch from Apex - one time use, and I made a DIY fluid with nitric acid per your article. Both reported properly. My pinpoint pH probe was a little off, but the apex probe was dead nuts.
.


Nitric acid? I don't recall any standard with it.

Boric acid?
 
I confused things. Your DIY was for the alk test.

I used these first - http://www.bulkreefsupply.com/milwaukee-ph-calibration-fluid-single-use-packet.html - and they were purchased in October. I checked against 10.01 and 4.01 per instructions.

I then used DIY standard solution of a 4.0pH. I didn't prepare it, so I'll have to confirm what my friend used, but I thought he said nitric acid. Whatever it was read 4pH after calibrating to the milwaukee solutions.
 
I confused things. Your DIY was for the alk test.

I used these first - http://www.bulkreefsupply.com/milwaukee-ph-calibration-fluid-single-use-packet.html - and they were purchased in October. I checked against 10.01 and 4.01 per instructions.

I then used DIY standard solution of a 4.0pH. I didn't prepare it, so I'll have to confirm what my friend used, but I thought he said nitric acid. Whatever it was read 4pH after calibrating to the milwaukee solutions.
Think it's better to use 10.1 and 7.1 to calibrate, that's what I do for my handheld Milwaukee pH meter..
Since we are testing between that range
Oops, Forgot some zeros 10.01 and 7.01
 
After 2 daysdosing with baking soda, my alk is stable and my ph has peaked around 8.35, so it appears that it may be a viable solution.

Still not sure why the pH started rising, but I guess it doesn't matter if this works
 
I'm glad this is resolved for you. :)

FWIW, pH is not a complicated issue. Only two things determine pH: the alkalinity and the carbon dioxide level in the water. So any time pH is off, one of those (or both) is the reason (assuming it isn't testing error). :)
 
Yeah, that's why I was perplexed. I'm wondering now if there has been a change in the air in our house - or at least the air flow in/around the tank.

In any event, all appears to be well, and I should be back to maintenance-minimal tank enjoyment. Thanks.
 
Sounds good.

FWIW, I noticed a big change (downward) in tank pH when we got new storm windows. It had previously been running 8.35 to 8.55 for years due to my use of limewater, but it dropped substantially lower after the new windows.

Happy Reefing. :)
 

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