Alkalinity dosing pump help...

GREEF stricken

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hey all, I would be greatly appreciative it's several people could chime in and give me some guidance on what time of the day I should does my alkalinity? I have decided to go with 46 mL per day over six doses.

Do I do this hourly for six hours? Or every two hours for 12 hours? Either way when do I start? What time of day do I begin that schedule?

Thank you

GS
 
Roger that. I am currently trying to disperse 46 mL once an hour at the top of the hour every hour of the day. However, I am seeing the large dips at night and I wanted to try and combat this

GS
 
So that's a good reason to dose 24/7. it also spread the pH boost into the time when pH is lowest (at night; which is good).

Some people find more demand during the day, so you might be a little heavier during the day.
 
Is a relatively new reefer forgive my ignorance, but I'm pretty logical at my core. I'm assuming a larger consumption during the day might be relative to having corals that thrive in highlight? That's their growth and processing of the supplements takes place when the lights are hig is a relatively new reefer forgive my ignorance, but I'm pretty logical at my court. I'm assuming a larger consumption during the day might be relative to having corals that thrive in highlight? That's their growth and processing of the supplements takes place when the lights are on?

GS
 
Is a relatively new reefer forgive my ignorance, but I'm pretty logical at my core. I'm assuming a larger consumption during the day might be relative to having corals that thrive in highlight? That's their growth and processing of the supplements takes place when the lights are hig is a relatively new reefer forgive my ignorance, but I'm pretty logical at my court. I'm assuming a larger consumption during the day might be relative to having corals that thrive in highlight? That's their growth and processing of the supplements takes place when the lights are on?

GS

A more complex question than it might seem. :D

It is likely that corals take up more alkalinity during the day (which is an empirical observation of some reefers) due to photosynthesis happening then. It might possibly just be that the tank pH is higher then.

However, the exact reason alkalinity is taken up then is not 100% clear. There have been papers that showed more skeletal extension at night, and skeletal growth is the primary place where the alkalinity ultimately ends up. That may have been an incorrect scientific paper, or perhaps it depends on the species of coral. Others papers, like the one below from 2014 show equal day and night growth:

http://www.ncbi.nlm.nih.gov/pubmed/24511631

from it:

"However, in our study, the average night-time extension rate (visualized in three successive 12 h pulses) was similar to the average daytime extension (visualized in the initial 12 h pulse), in all growth directions and skeletal structures."



Bicarbonate is taken up during photosynthesis, and bicarbonate is the largest component of alkalinity. But photosynthesis does not actually use the alkalinity, just the CO2 that is taken from the bicarbonate:

HCO3- --> CO2 + OH-
bicarboante --> carbon dioxide plus hydroxide

i doubt corals can store much hydroxide, but they perhaps can store it as carbonate, which they do use for skeletal growth:

OH- + HCO3---> CO3-- + H2O

I discuss some of these issues here:

Aquarium Chemistry: The Chemical and Biochemical Mechanisms of Calcification ? Advanced Aquarist | Aquarist Magazine and Blog
http://www.advancedaquarist.com/issues/apr2002/chem.htm
 
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I like to spread my dosing out evenly over the 24 hr. I'm set up to dose 5 ml every 1.5 hour for a total of about 80ml per 24 hr. I also dose Ca I have it to cycle 45 minutes after the alk seems to work pretty good for me
 
I run my dosing from 6 in the morning to 12, then run my calc from 1 to 9 ,then i run the rest from 10 to 1 in the morning gives me about a 1 degree ph swing, randy not sure if im right please correct me, there were studies that corals calcify quicker at lower c02 levels during the night?
 

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