Well, anything can fail...
I don't recommend using a reservoir large enough to crash your tank... With any ATO.
And that rules out connecting your rodi unit as well..
On my biocube 14 I have a 32oz reservoir hidden on a shelf below the tank, about a weeks water but not enough to flood/crash.
My 120g display I dose kalk, it's set on a timer to run 2 minutes every half hour, so it can't ever dump the entire 10g reservoir.
The only problem I've heard of is if you get a leak in your tubing, so if you have mischievous cats or dogs make sure they don't have access to chew it up.
I don't get a half inch variance, it's usually less than a quarter inch difference. I have my line marked in the sump, and check it daily when I clean the skimmer neck.