https://www.reef2reef.com/threads/flippers-reef-125-gallon.317425/
First page of my build thread shows a little of what I did using rods and quikrete hydraulic cement.
This is what I would do, a combination of of rods used for main part of structure and hydraulic cement to fasten smaller pieces to add detail and hide spots where rods may show.
I personally do acrylic rods always so I can go up w/ good stability and fill in small rock pieces one my structures are in place.
I keep any wet established rock submerged in brute cans, and I make a table template of my tank w/ over flow, and I just start pulling out pieces and see what fits or mates well, then drill, masonry bit, sized slightly bigger than rods for some wiggle room, stack.
One I have a island or pillar structure I dunk it in another brute to and move on to the next structure.
Another thing I advise is to protect your glass panels.
I place cardboard inside tank to make sure a rock does not shift or drop scratching glass while scaping.
After I have my main structures in I'll fill in w/ small pieces.
There are a number of ways to hide oveflows, people make panels w/different mixes of either foam or crete and aragonite and small pieces of rock, but I've never bothered myself, usually my structures will kinda hide that.
My front page shows how I did mine.
https://www.reef2reef.com/threads/rebirth-of-my-octocab-tank.204901/