I am late to the party, but if not said already, make sure and keep your aeration up. The growing bacteria will consume some oxygen, which is another reason to have an oversized skimmer. Keep the surface agitation up.
Once it gets going, your skimmer should stink like a dead skunk that has been on the highway for a week at 100 degrees. If it does not, then you might need to up the dose. You will likely need to empty and clean the cup every day or two. It should skim dry with ease and not overflow. The drier parts should get sticky.
Do NOT up the dosage quickly or your bacteria will multiply too quickly, use all of the oxygen and suffocate your fish. It has happened, so be careful.
Organic Carbon is like high tide and it lifts all ships... good and bad bacteria alike can use it to multiply better. Fish with bacterial infections seem to do worse as well as some other stories that have been posted. These are mostly outliers and dosing organic carbon is relatively safe in the right application, but something to keep in mind.
It takes a while for the bacteria to start to multiply, live and then die. You mostly skim the dead ones, so be patient and wait for the process to work.
Biopellets do release carbon, just like any other kind of organic carbon dosing.... but different, not ethanol, vinegar or sugar, but a different kind. Without more carbon, it doesn't work.
I just used sugar in my FOWLR - cheap, pure and easy.
Your skimmer should look something like this if you are doing this right.