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Pretty normal in my experience. I've used Kent both Kent and Reef Crystals and I usually clean the can with vinegar every other fill. Some say it's iron precipitate but regardless it seems mostly harmless.
I have one Brute with salt and the other with RO/DI and the RO/DI container never gets the film.
I have the exact same experience with my brute cans. I was under the assumption that it was something in the salt mix personally but I could be wrong. Usually I only see the film build up if I leave salt water moving in the can for more than a day.
I have read several places that the brute cans leach phosphates, leaving your water smelling like urine.

