A sulfur denitrator can be dangerous only if mismanaged by the user. Because of the high risk for human error, we do not advise sulfur denitrators to be used in a live support system.
In principle the produced gasses are N2 but if not managed correctly most of it may be H2S but for sure you will be able to tell the difference.
In most cases when it goes wrong the effluent flow rate is very low which means the danger for the tank is limited. This because such denitrators are managed as it where carbon based denitrators and are kept anoxic. This leads to very high possible nitrogen removal rates at high nitrate levels and very poor results at low nitrate levels. One can only remove what is supplied!
For example, a 1000l reef tank producing 1ppm nitrate daily . To lower the nitrate level on must remove >1000 mg nitrate daily. We desire a nitrate level of 2ppm! When the system contains 40ppm nitrate the daily flow rate must be at least 25l/day, depending on the nitrate content of the effluent. no problem! If the tank contains only 4ppm nitrate the flow rate must be at least 250l daily 0 nitrate effluent to remove the same daily production. To bring the nitrate level to the desired 2ppm the flow must be doubled to at least 500l daily 0 nitrate effluent. This of coarse if the daily nitrate production stays steady at 1ppm daily. 1ppm daily is not that much, if the daily nitrate production increases to 2ppm the denitrator must be able to handle a daily flow of the total tank volume. The fact a lot of users aim at 0 nitrate in the effluent increases the risk for human error and for stimulating sulfate reduction considerably. it is very important nitrate is available in the reactor. And very important if the reactor is kept anoxic, the quantity of oxygen to be removed increases with increased flow.
Just to show such a denitrator must be big enough!
As such device is kept anoxic the flow rate can not be managed to follow the nitrate content and can not be increased to remove the daily nitrogen overproduction daily. In most cases, the denitrator will reach its limits long before the desired level of 2ppm is reached. If not recognized such a reactor is easily mismanaged.
Using BADES-reactors or BADES-biofilters this is easily manageable, BADES reactors are not kept anoxic. There is no need for the reactor to be kept anoxic for stimulating Biological Autotrophic Denitrification using Elemental Sulfur ( BADES). There is no need for a reactor as the process takes place in any normal nitrifying biofilm
Everything about using BADES. ref:
http://www.baharini.eu/baharini/doku.php?id=en:badess:start&rev=1589450735