Yeah, Randy is right. Some of the “old” salt will always remain. At 30% water changes, you have 70% remaining after 1 change, 49% remaining after 2 change, about 34 % remains after 3 changes, about 22% after 4 changes and 15% after 5 changes.
The thing is that an old Ca ion is just as good as a new one. Ions don’t wear out. Generally you can measure and replace most macro nutrients by dosing: Ca, ALK, Mg, nitrate and phosphate. It is the micronutrients that water changes can replace that and exporting any accumulating wastes that normal export systems don’t get. Water changes are a brute force approach but they are very effective.