Chemistry and Photo-sensitivity

Tenshoa

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First let me preface that I've been a reefer for quite some time and am fairly knowledgeable about water chemistry and the dos and don'ts of this hobby. I say that so that we can move beyond the typical tech support rigmarole "did you check to see if your power cable is plugged in" sort of responses.

I would also like to avoid the typical regurgitated anecdotal advice is possible. :)

What I am interested in is the relationship between water chemistry and hyper photo-sensitivity in corals, particularly sps.

I know that for instance, there is evidence that high phosphates OR (not sure which) the rapid reduction of high phosphates plays a part in hyper sensitivity. I have witnessed this with my own eyes in one of my tanks whereas sps began bleaching until introduced to low light for a moderate period of time, slowly ramping back up to normal levels. However, the bleaching did not appear to be the typical type of bleaching that you would witness under normal conditions containing too high of light intensity. It was more of a localized bleach, where the branches of certain acropora facing up and the surfaces of montipora most exposed to light would appear lighter as if "sunburnt". Difficult to explain.

What I would like to learn is whether or not there are other factors within the water chemistry that would result in the same sensitivity.

I am seeing signs of this on certain acropora colonies in my tank, where they are dark at the base and sides of branches, but extremely light on the surfaces. It is extremely similar to what I once experienced when high phosphates resulted in high sensitivity. The flesh is still good as I can look at it under a loupe.

My water parameters in this particular tank (I have 5) have been very stable and have not deviated in months. These parameters are also very intentional so I am not going to get into a debate about Low Nutrients vs High Nutrients since I have done this long enough to know what my corals look best with. These parameters are checked multiple times per week and NO3 and dKH are checked daily

Tests performed with Salifert unless otherwise specified and periodically checked against a different Salifert test kit for accuracy:

Alkalinity: 8.6 (no more than .4 variance over past 4 months and less than .2 variance in any given week)
Calcium: 490 (I am in the process of reducing this as we speak)
Magnesium: 1480-1500ppm
NO3: 7 (no more than variance of 4 over past 4 months and less than 2 in any given week)
PO4: 0.0 (Hannah checker and Salifert)
Temp: 77.6 - 79.1 daily (chiller and heater are hooked up)
PH: 8.11-8.31 from day to night (no kalk is currently being used or has been used for past 4 months)

Lights are ATI Sunpower 6 bulb (5 blue+ and 1 purple+) 12" off the surface of a 12" deep frag tank plus a blue Reefbrite XHO. Both fixtures 60". Two blue T5's on from 9:00 to 21:00, remaining bulbs from 10:00 to 16:00. Bulbs are 6 months old.

Salt is Red Sea blue bucket

Refugium has chaeto

Trace Elements are tested for and dosed with Red Sea kits

2 reactors, one with carbon, the other with Rowaphos. Each changed monthly.

Flow consists of one MP40, one Jebao PP15, two Jebao RW-8, and 2 Koralia in a 60 x 24 x 12 tank. Plus two returns run by a Deepwater Aquatic DC10 Return Pump. Skimmate via Reef Octopus is set to dry skim. 200 micron sock is utilized. Polyp extension is excellent.

Water changes weekly-ish

Fish fed once per day with PE Mysis and Rods Herbivore. Corals fed twice per week with mixture of ReefRoids, Phyto, Reef Chili, and Aquavitro Fuel is dosed twice per week per instructions.

This system is plumbed into a 40g breeder tank as well that utilizes an Aquaticlife 4 bulb t5 fixture that sits directly on the tank. I have only used 2 blue+ bulbs as of late and have placed troubled corals in this tank with good results. The interesting thing is that some of the acro colonies (in the large tank) are starving for more light and show no signs of bleaching. And some corals are coloring up beautifully. All corals have been inspected regularly under high magnification and no signs of pests are present. All have been thoroughly dipped and/or quarantined using Bayer.

I have exhausted all ideas on chemistry with the exception of one, which are aluminum levels. Possibly as a result of the Rowa. I do not have a test for this.

Any thoughts would be greatly appreciated.

Kind Regards,
Pete
 
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Salt is Red Sea blue bucket

As I started reading this I thought "I wonder if he's using RSBB..."

Look into posts regarding this salt and SPS photosensitivity in 'that other huge reef forum'. RSBB is alleged to have a much higher than normal level of manganese when freshly mixed (~40x NSW), but won't measure high in the tank water due to rapid assimilation, oxidation and precipitation.

Personal experience: After a member warned me not to use this salt at 100% (especially not for SPS dominated tanks), I split it ~50/50 with an RC/IO blend and I still had to turn my lights down ~10 -15 due to obvious coral sensitivity (lightening of SPS surfaces facing upward, reduced expansion in Mushrooms, etc.). I then cut it in half again to 25%, mixed with various other salts, and I was able to increase light intensity back up to the previous levels I had used before I started using RSBB.

This was all a while back and I don't if the salt still has high manganese levels when freshly mixed (and it's not the only one, apparently). But it's definitely something to consider, IMO.

Hope this helps...

Ralph.
 
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You have got to be kidding me. I never heard of this. So let me thicken the plot a little. This started occurring right about the time I switched to blue bucket. Previously I was using the pro salt, but I didn't like how high it mixed my alkalinity at. I was struggling to keep it below 12. I will definitely look into it. Who would have thought? I've been sitting here scratching my head for weeks since I haven't done anything that I haven't done in any of my other tanks.

Wow.

Thanks Ralph!
 
Link PM'd.

This may, or may not, be the main issue...or it may just be a contributor among other factors, but it's a place to start at least.

The nice part about this is that cutting the RSBB and then mixing with other salts is an easy operation and not all that expensive. Very interested to see if just this one change, without any other changes, makes a difference.
 
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For sure. I was just about to buy another bucket of salt. I'm tempted to try the regular Aquaforest since its levels are very close to NSW and closer to how I like them. I will definitely let you know how things turn out.
 
FWIW, back to the general question, photosensitivity is one of the hypothesis of why burnt tips happens when alk is high and nutrients are very low.

The hypothesis is that skeletons grow faster than the tip tissue, making it thin and more susceptible to damage, by light or other factors.
 
Yes. but these are definitely NOT burnt tips. Alk is extremely stable as noted and nutrients are plenty. Take a look at the attached photo. This is one example. You will notice where the purple gets very pastel. The tissue is showing signs of photosensitivity. Where the flesh gets darker is where there is less light.
FWIW, back to the general question, photosensitivity is one of the hypothesis of why burnt tips happens when alk is high and nutrients are very low.

The hypothesis is that skeletons grow faster than the tip tissue, making it thin and more susceptible to damage, by light or other factors.

IMG_4623.JPG
 
There are lots of things that can stress corals (including chemical toxins or lack of needed trace elements), and when stressed, corals can become more sensitive to other stressors, such as light. That said, what exactly may be happening here I do not know.
 
I have experienced this myself and I am currently running my Radions at 40% instead of the normal 70% or above. My corals started to bleach and I lost several of them before catching the issue. Triton results showed 0 po4 and 0 phosphorus. Dropped my lighting intensity and got my PO4 up to .02 and everything is recovering quickly. So I would agree that very clean water has an effect on par sensitivity.
 

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