Thanks for the help. I have a 90 gallon dt and a trigger 36 sump. I'd estimate 100-110 gallons total water volume. The Skimmer is an SCA 302 rated to 180 gallons. It was pretty highly reviewed. I tried adding more water to the outer container. I am starting to see a slight color change now at the top of the canister. My pH is up around 8.0 right now. I am testing using an Apex double junction probe that was recalibrate today. The probe is only 1 month old. I also double check with a Red Sea pH kit. As far as the jump up in the last couple hours I am Not sure if adding more water helped or if it's the fact that I had some windows open today. The house is typically sealed up most of the time.
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