Although the 13 fish seem very little, right now there is an imbalance between the waste generation from the fish and waste processing from the microfauna. Here i don't just mean the nitrifying bacteria you can dose from the bottle (remember that is only good to convert the toxic ammonia into no3, but does not get rid of no3). The waste No3 and Po4 can only be processed and exported with time with more maturing tank as your bacteria and other micro fauna catches up. the brown algae is the first sign of this imbalance. However, since your volume is big and you have new rocks, this reaction is muted b/c 1) it will take a while for the imbalance to really tip the scale and 2) the new rocks will absorb a portion of the waste, giving you a false reading when you test your water for NO3 and Po4.
your fish will likely be OK as long as you keep up with nitrifying bacteria to prevent ammonia poisoning, but all that accumulated unprocessed waste will have a very delayed reaction on when it will eventually rear its ugly head in your tank. Think of it as a big diaper - It will feel fine for a while, but eventually that diaper will be full and will stink up the place. keeping up with good husbandry and you'll have 5 to 8 months of relative peace until your rocks saturate with nutrient and you end up bad GHA outbreaks.
not saying what you did is wrong - there are different paths forward. others on the post prefer slow and steady b/c the nutrient/waste cycle and balance is a very delicate thing in our closed systems. Accelerating the nutrient load will make your tank have bigger ups and downs in its path to maturity but may get you there faster as long as you keep up with good water changes, manual removal of nuisance algae (there will be a LOT), avoid the temptation of "miracle bottle" fixes, give your micro fauna to catch up and establish itself, let you system run its course. Its like putting rocket fuel in your car - you car will probably go faster but the ride will be bumpier ( with a small change it will blow up.)
Also got a pic of the purple stuff? is it crusty or "carpety"? might actually be purpose cyano rather than coralline.