This is exactly what it is meant by outcompete. When diatom compete for space and nutrients with dino, as well as producing allelopathic chemicals, they can help to bring dino under control.
Diatoms are harmless, in fact, great food for corals and inverts.
@martin3490, I would target about 4ppm silicate for a start and dose to keep it there to induce diatom bloom. Once the diatom started to take over, I would dose and maintain silicate at about 2ppm until dino is mostly gone.
Do ensure silicate dosing is appropriate for the species of dino you have. Also keep in mind the pH and Alk impact of silicate dosing.