As mentioned by someone earlier you may want to run the pex tubing directly into the sump. I know people have done this in the past. I just put a radiant heat system in my house, so I did a lot of research on this subject.
There are other things needed as well. You need an air seperator, fill valve/back flow preventer, mixing valve (to control temp to heat exchanger/pex in sump), and expansion tank. You also possibly may need two pumps, one to act as a system loop pump and the other lower flow to circulate water to the heat exchanger/pex in sump. With too high of flow to a heat exchanger you may not get the change in temperature needed for the system to work properly. Also the on demand unit needs to be able to do radiant heat per the manufactures specs. Not all units can be used in this fashion. Plumbing should be done in copper prior to the heat exchanger/pex in sump. All plumbing should be insulated as well.