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The paint increases surface area as does anodizing.As a practicing professional materials engineer, let me weigh in.
From a purely thermal point of view, best option is to apply a thin coat of a matte black paint. Stay away from glossy finishes.
Heatsinks are overwhelmingly convective as far as heat transfer goes, so it won’t make a big difference, but a matte black paint will have a much higher emissivity than the “silver” aluminum for radiative transfer. A thin coat of paint will only create a negligible effect in terms of insulating against conductive heat transfer.
Cheers,
Terry.....
( New quote)
Under natural convection conditions, the performance of a heatsink with a black surface will be 6% to 8% better than that with a plain or bright surface. However, this differential disappears under forced air conditions.
source:
or:
Scott has right:
Heatsinks work more by convection than radiation so colour isn't such a large issue as surface area, orientation of fins and good air flow
The emissivity of clear anodized is 0.76 to 0.84, close to black (0.82-0.86)
and the plain is just 0.04?
Is that correct?

