You can calculate the volume of water going into the sump when the pumps are turned off. I'll use inches in this example. You need to measure the length and width of the inside of the tank and now the depth the water would drop when the pumps are off. If the lowest point are the saw teeth in the overflow, then it's there. If you have a return line that is lower, then it's there.
Now simply multiple length x width x depth to get cubic inches.
Now multiply your cubic inch number times 0.004329 to get number of gallons.
You can do the same calculations to determine the amount of available space in your sump to accept this volume.
Here is an actual example with my tank. The length is 59 inches, the width is 17 inches and the saw teeth are about 3/8 inch below the water.....I'll round that up to a 1/2 inch to play it safe.
So 59 x 17 x 1/2 (0.5) = 502 cubic inches
502 x 0.004329 = 2.2 gallons
Hope this helps.