Kalk doesnt evaporate. Adding kalk also adds fresh water.
The idea is to match the mount of water that evaporates out of your tank, with kalk mixture (Kalk and ro water). This assumes that you use that much calcium and alkalinity. The reactor and a dosing pump approach to dosing kalk allows you to slowly add a measured amount of Kalk mixture through out the day. This levels out the peaks and valleys and unpredictable doses that kalk in top off water creates. If you are dosing 2 gallons of kalk through out the day with a dosing pump it will naver change. If your ato pumps in 2 gallons of kalk, it will give you peaks and valleys and if you evaporate 2.5 gallons it will be an extra .5 gallons of kalk which will drive your alk and calcium up.
Since you have a trident, life got alot easier! I would turn off your 2 part dosing and your ato. Then set the dos to dose 1.5 gallons of kalk over 24hours. (5677ml). Have trident measure as normal for 24 hours. If you alkalinity goes up, you know you need to lower the amount of Kalk mixture dose. If your sump water level raises, you will have to lower the kalk mixture dose. If your alkalinity lowers and your sump level lowers, then you can increase the dose of Kalk mixture. Once you either meet your alkalinty needs, or you raise the level in the sump, you have to hold the kalk mixture dose where it is (this is the maximum amount of Kalk you can dose to your system). If you hold the Kalk dose due to the sump level rising, then you will use 2 part to raise your alkalinity and calcium to the level you keep it at.
In an ideal world, you ATO will never kick on because your tank will evaporate the same amount of water every day and you have tuned you kalk reactor and dos to dose the Kalk mixture in the same volume as water evacuating. If you spring a leak or forget to turn off your ato during a water change, the ato wont dump large amounts of kalk mixture into the tank.
Once you have the Kalk reactor and Dos dialed in, then you can turn on the ATO.
Does this make sense?