As an occasional treat, it should be fine (especially for herbivores). Duckweeds have a lot of vitamins, minerals, omega 3's, and are a good, complete source of protein. They also act like mineral "magnets," soaking up divalent cations (1) (like Mg) up to ~10% of the plant's dry mass. Wolffia would probably also be a great addition, with a nearly identical nutritional profile, but smaller size for smaller mouths.
Downside, is duckweeds also produce oxalic acid / calcium oxalate (like kale or spinach). This can cause kidney stones in humans that are sensitive, and has caused ill effects on salmon feeding trials (2) (carnivore). Tilapia and white shrimp, on the other hand, perform well on high inclusion rates of duckweed in their feed. There is a relation between oxalic content and Ca in the growth media, so softer water would be less risky.
I'm a bit of an expert in duckweed, so i'll answer whatever I can that doesn't involve IP or trade secrets.