Theoretically, any balanced two-part will provide just the right amount of both calcium and alk for growing corals.
There will never be a higher consumption of one or the other due to coral growth, based on simple chemical stoichiometry.
Coral skeletons are made up of calcium carbonate (plug Mg and other elements, which can be ignored for now).
Calcium carbonate is CaCO3; one part calcium to one part carbonate alkalinity.
Abiotic precipitation of calcium carbonate on heaters, pumps, etc should also adhere to this 1:1 ratio.
However, this is the theory, but the experience of reefers is often quite different.
I have never heard a satisfactory and clear explanation of how an imbalance arises.
It does though, frequently, and usually results in a deficiency of carbonate alk, which requires increased dosing of that component.
I used to think that this was due to CO2 gas leaving the water, resulting in a drop in alk.
However the science indicates that alk content in saltwater cannot change in this way.
I suppose imbalance could be due to carbonate combining with other elements than calcium, but I've not heard specifics.
So, bottom line is that, if your starting levels are appropriate, you should start with balanced dosing.
But don't be too afraid to 'uncouple' the dosing if the need to do so appears to be present, based on future testing.
Also note that calcium reactors, which may be the best dosing method overall, always dose in the balanced ratio of 1:1;
this is because they dissolve already formed coral skeletons for both calcium and alk. (And this also provides magnesium.)
Here's another thing that isn't obvious and that many people don't understand right away.
Just because calcium and alk are consumed in a 1:1 ratio, doesn't mean that they naturally exist in seawater in a 1:1 ratio.
Far from it. The concentration of calcium in seawater is proportionally much higher than the concentration of alk.
Each 1 dKH drop in alk only uses up 7 ppm of calcium.
So, for example, if you somehow exhausted all of the alk in a tank starting at 8 dKH, the calcium level would only drop by 56 ppm.
So your alk would then be 0, but the calcium level would be almost unchanged, around 340 if starting at 400 ppm.
This is also why alk levels are generally more volatile than calcium levels; there much less of it in the water to start with.