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Kalk and boiling water works well. You will never get the all with any product, so some Peppermint Shrimp from the Florida Keys or a suitable fish are a good idea, but they even come back if these die since there seems to always be one that is hidden out that can repopulate.
Vinegar adds organic carbon and can fuel a bacterial bloom if you use too much. In small does, it is probably OK, but larger doses can create such a large bacterial bloom that they use up all of the oxygen and can kill fish.
Kalk can raise your pH if you use a lot. Turn the flow pumps off for an hour and let the kalk set up and get hard and your pH will barely move.

