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I don't believe that calcium gluconate will have a meaningful impact on alkalinity. I would expect that iron gluconate would also have a minimal impact on alkalinity.I wondered if Fe-gluconate behaves similar to calcium gluconate (like seachems all-in-one), to also boost alkalinity. As Fe-citrate will also consume alkalinity....
I think you won’t be adding enough to notice the alk effect. Also, the iron itself will deplete alk if oxidized from ferrous to ferric iron.

