There are a few things you need to do to determine what is wrong.
1 Put a straight edge on the trim of the tank
2. put a straight edge on the top of the stand.
3. Determine which one is not straight..
I have had tanks where the black trim is not put on properly.
If its the stand that is out, Figure out if its out of square Rocking on the floor causing it to be racked, Sitting on tack strip.. Depending on how you built the stand. If its like many way OVER BUILT. you might not be able to shim it due to no flex.
If you have it shimmed and its sitting solid to the floor on all 4 corners, Then my suggestion 1/2 plywood , screws and shims .. Cut a piece of 1/2 plywood to fit the top of the stand.
Find the highest point on the top of stand structure and mark this as your starting point.
Put the plywood on top and run a screw into this area. Using straight edge/ level that is the full length of the stand start shimmer and screwing the plywood to keep it flat across side.. then to each end then the other long side..
If the plastic trim is what is out.. LAY PLYWOOD on the top of the stand.. shim under the plywood to remove gaps and insure tank is level.. Gently raise tank up and screw down..
Your issue is why i DO NOT Recommend people to build tank stands with ROUGH Lumber especially 2x4 without proper tools , Running each edge thru a table saw to insure its TRUE and Straight..
I Will add bee weary of any advice on the internet including mine, As i cant see the whole stand or know the entire situation. The above is from my educated guess .
Sorry for such a long post .I hope its detailed enough to help you make the right choice of adjustment for your situation...
Good Luck
Erica Renee