First have to say great plumbing job!! Very, Very neat and yes the 45 degrees are much better then 90.
The output of your pump the pump is 1.25" and you reduced it to 3/4" right out off the pump therefore you already will have head loss.
For example if you were using 0.75” tubing at a length of 5 feet and are trying to achieve a flow rate of 1000 gph, you would have an additional 3.25 feet of head pressure (0.65 x 5 feet) on your return pump. Again this is not 100% exact but provides and idea of the head pressure that needs to be calculated when using different size piping.
For example ¾” Tubing and Smaller: Add 1 foot of head pressure for every 90-degree turn.
For example 1” Tubing and Larger: Add 1/2 foot of head pressure for every 90-degree turn.
Filters: Approximately 2 to 4 feet of additional head pressure
Chillers: Approximately 2 to 4 feet of additional head pressure
UV Sterilizers: Approximately 1 to 2 feet of additional head pressure
Total Head Pressure = Pump Lift Distance + Diameter and Length of Return Tubing + Pipe Fittings + Inline Equipment
Good Website to helps calculate your head pressure:
https://pentairaes.com/pump-calculator
It is best to use as large of a tube or pipe that is possible as this will minimize the amount of head pressure on your pump, and allow you to use smaller pumps.