Maybe Ralph could spend just a moment or two more to read a little more closely and not go off with half-correct facts? Details really are important.
1) Per the OP's first picture it's near some type of "Railroad Tie or Pressure Treated Landscaping Timber" and doesn't appear to be in or in the middle of the woods. Those aren't usually found "middle of the woods" but near urban areas where chemicals (especially herbicides for weed control) are very common and likely to be used. Many area management/landscape companies will use "Chemical Weed Control" for speed and economy. Spraying Herbicide along the "Parking Area" (which is where this was located after all) is totally feasible.
2) Then we have the OP's very own statement of
"It wasn't deep into the woods, it was the edge of a park, over the guardrails leading to the wooded area." Again, the OP's details matter in this conversation and shouldn't be discarded or turned around.
So it seems that Ralph and Sue could very well be dealing with some rocks that "potentially" are laden with chemicals etc since they were NOT "in the middle of the woods" at all. With the actual facts at hand, this " bizarre chemical scenario" is a lot more possible and a lot less comical as least from my narrow point of view.
LOLOLOLOL
@SueAndHerZoo I don't mean to bring a rain cloud to your parade in the least. I would just hate to read a post where you had a total tank crash in an attempt to save a few dollars on "questionable" rocks. I genuinely HOPE they are the cleanest and purest rocks on the planet and you get many years of use and enjoyment out of them.
I tend to give advice leaning heavily on the "cautious side" just because it's the safe and right thing to do. It's easy to sit behind a keyboard and give advice to "go for it" if you have no skin in the game but that's not always the "Right" advice for the situation. I wish you nothing but the very best of luck and success with your new found treasures.