It has helped, but not to the extent I was hoping. I'll tell you what I've found so far.
I had a small tank that was just housing corals and a pair of clowns. I couldn't afford to buy more than a few at a time, so the holding tank let me accumulate a decent collection while I got my main tank ready.
The holding tank: No skimmer at all, and the chaeto ball was in the holding tank with the fish and corals, so with that in mind... Daytime pH with the light on (Kessil A360) and chaeto in the tank would climb to 7.95-ish, and at night, fall to 7.75-ish. Lower than I like, and I didn't realize it at the time, but the light + chaeto ball was the majority of the reason I would see a climb during the day.
If I opened a near by window during the day, in an hour or so, I would see pH climb to 8.05-ish, and hold there for several hours after closing the window. So...I was expecting at least a steady 8.0 with a fresh air line to the skimmer in the main tank once it was set up, but I didn't get that.
The main tank: Dual Kessil a360's, plus a pair of 48" t-5's for light. No chaeto in the display tank.
Chaeto in the sump, opposite light cycle to the display tank, and lit with a kessil H380. Skimmer is an Omega 130, and plumbed to fresh air. Daytime pH is steady at 7.95, and night time climbs up to 8.4 until my apex turns off the light! That chaeto coupled with a H380 is a pH machine!
I did an experiment: I disconnected the fresh air line for a day, and didn't turn on my refugium light. The pH that day was 7.9-ish, and that night it dropped to 7.85-ish. That's an improvement over the nighttime holding tank, and probably would have been better in the day too were it not for the chaeto. Still, it's a marginal improvement at best.
The takeaway: Chaeto lit with the corals in the holding tank = higher daytime pH. Chaeto lit with a much more powerful light on an opposite cycle of the corals in the display tank = super high nighttime pH.
On my next build, I will probably skip the fresh air line, and opt to run dual refugiums! The way I see it, the chaeto + H380 can get me to 8.4 easily, so if I run dual refugiums on opposing schedules, I should be able to hold a high pH all the time.
I just don't think the skimmer pulls in enough air to equal the natural gas exchange that happens with an open window, but that's just my theory
Hope that clears the fresh air.