As I said (or meant to

), a tank full of growing stony corals combined with a dosing regime that is less than once a day
will cause alkalinity fluctuations sufficient to do what you're seeing. I've never had a pH meter, but I suspect the varying pH that's allowed when alkalinity dips is one player in stressing out your corals. There're probably other issues and stressors too though.
Alkalinity is meant to be stable and it is one of the least-present elements in seawater so it has by far the greatest "ability" to fluctuate and fluctuates more quickly, and has a much greater effect on overall water chemistry than (e.g.) calcium or magnesium level changes you're seeing.
As I said there are other variables so my example may not apply directly to you, but back in the day of halides when I'd accidentally let alkalinity dip under 2.5 meq/L, my corals would start losing color almost immediately, sometimes even losing a little tissue. I tested religiously back then and logged my results...and saw this trend repeat verbatim after various mistakes through those years.
Without further ado you should use a meter or drip test (like Salifert) and begin testing your alkalinity at least once a day, followed by any dosing adjustment needed.
Make the adjustments slowly, using drips no faster than 1-2 per second. (Volume of adjustment doesn't matter too much as long as the adjustment is made slowly like this....do not rush.)
3.0 meq/L is a good dosing target, especially when you are doing this by hand, as it gives you an added safety margin vs NSW levels.
Maybe test again a little while after dosing to confirm the results, but aside from satisfying your curiosity that's not really necessary
because you are logging your test results, right? The results will be apparent in the trend.
I mean it though....
test and
dose every day,
log your test results, and you'll have fewer coral mysteries in your tank - I guarantee it.
P.S. Stop using ozone IMO....unless you're already well versed at interpreting ORP readings and have a quality meter AND understand how O3 works with (e.g.) copper and other things possibly found in your water.....I don't recommend it. If you're wrong or even just mistaken in your employment of it, this could also easily cause RTN all by itself. Ozone use may be a sensible protocol in (e.g.) a wholesale or retail environment, but should be utterly redundant in a healthy reef. It's conducive to a sterile environment, not a healthy one....important not to confuse the two as they are so often. Healthy != Sterile (Sorry.)
P.P.S. ULNS is a system of removing money from your wallet. It's also what some people call an aquarium system that is neither overstocked nor overfed.

