IMO most gas exchange happens in the skimmer and in my case I got pH down to around 7.8 - 7.9 in the morning especially if we had grand children sleeping over. It was so sensitive to the extra CO2 in the living-room that I could see the exactly time they wake up in the pH curve of my aquarium

. I redirect my skimmer air to the outside and now I can´t see on my pH when the grandchildren awake

. The pH drop stops around 8. I use Triton Core 7 as "balling" solution and it use sodium carbonate as alkalinity compound. Sodium carbonate drive up the pH and for some time - I dose it only during nighttime. My pH varies between 8.2 and 8.5 during this time but I could not see any good or bad effects of this (according to pH) However - my KH vary a lot during the day - therefore I change tactic - nowadays I let the KH be rather stable and accept 8 as lowest pH. To be honest - I can´t see any differences at all.
As many have say here - do not chase numbers
Sincerely Lasse