High alkalinity but low pH

So, here is an update. I've tried running skimmer lines to outside the house, but the effect on pH is less than 0.05 pH units. The pH still swings between 7.8-7.9 at night and 8.1-8.3 during the day.

I've also been topping off with limewater regularly, and while the pH responds after a topoff cycle, the pH ultimately recedes at night.

I've also had windows open for longer than 48 hours when the weather allowed with little effect on pH. I would've thought 48 hours of aeration should be sufficient to lower inside CO2 levels if that were the culprit.

Last night, I aerated a sample of my tank water for more than an hour outside using an air pump, and the pH didn't even change 0.1 pH units...which got me thinking. I wonder if the low pH is the result of me living near a busy highway? There are no other large highways near my house, so this particular highway is heavily traveled. Excess CO2 in the area from the traffic would render the skimmer lines ineffective and would explain why neither opening the window nor aerating the water sample produced the desired results.

Another hypothesis is that the CO2 generated from carbon dosing is causing the low pH. However, I would've thought all those dosing carbon would have similar issues.

I'm considering a CO2 scrubber for my skimmer air line as a test. If the high ambient CO2 is the issue, I would think scrubbing the CO2 out of the inlet air to the skimmer should produce a noticeable difference. Thoughts?
 
I will be participating in an unplanned test next week. We will be out of the house for several days, so there should be no CO2 generators in the house. If high ambient CO2 is the cause of the low pH, I would expect to see some improvement next week. Guess we'll see!

Yes, people do report that, and especially the reverse: dropping pH during a party.
 
I'm considering a CO2 scrubber for my skimmer air line as a test. If the high ambient CO2 is the issue, I would think scrubbing the CO2 out of the inlet air to the skimmer should produce a noticeable difference. Thoughts?

Many people find it does, but with the limitation that the tank top is opposing it.
 
Many people find it does, but with the limitation that the tank top is opposing it.
Yes, I did think of that. If the diffusion over water surface contributes the same order of magnitude CO2 introduction as the skimmer, then a CO2 scrubber may have little noticeable effect.
 
Yes, people do report that, and especially the reverse: dropping pH during a party.
I observed the same thing over the holidays when we had many visitors over or anytime there are more people in the house than normal.
 

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