I'm not sure what you mean by "1 quarter size of mysis every 2-3 days". Do you mean a circle of mysis about the diameter of a quarter? If so, and this is the typical flat-pack PE Mysis, you're probably drastically underfeeding your fish. BTW, I'm think you mean you have 40 ppm "NO3", not "pO3".
Depending on how often and how much you change your water, it's not at all unusual to see a build-up of nitrate and phosphate in tank water over time. When you see established reef tanks where the owner notes nitrates of around 5 ppm and phosphates of 50 ppb, realize that doesn't happen all by itself. And as you've noticed, you don't control those parameters by underfeeding your fish and (usually) solely with water changes.
Instead, you need to do one of two things, or a combination of both, as an export mechanism. The first choice would be encouraging bacterial growth with some form of carbon dosing. That can take the form of vinegar/vodka additions to the tank water, or it can take the form of so-called "solid carbon dosing" in the form of a bio-pellet reactor. This will encourage the growth of bacteria, which your skimmer will then remove, resulting in lower nitrate and phosphate in your water. Since your nitrates are so high, I would caution you that you should start very conservatively with vinegar dosing if this is the route that you choose. In a 90g tank, I would start at 4mL of vinegar per day for a week, only adjusting upward after you've ensured that you're not going to get a severe bacterial bloom, which could make your tank cloudy and adversely affect your fish from lower oxygen levels. Note this is far below the typical "starter" dose of vinegar for your tank size.
The other alternative would be to start a refugium with macroalgae to consume the excess nutrients. This might be as easy as adding a light to your sump and adding some chaetomorpha algae, or as complicated as setting up a small auxillary tank connected to your main DT. Yet another option is to add a separate "algae reactor", such as the ones made by Pax Bellum, Skimz, and (soon) Tunze.
Finally, there is a third way, which is a dedicated sulfur or coil-type denitrator reactor. I don't recommend those unless you're an advanced aquarist. These types of reactors rely on anaerobic bacterial growth in a partially anoxic environment. If you're not careful, you can produce hydrogen sulfide from these types of reactors, which can nuke your whole tank in a matter of hours. In contrast, the first two methods are relatively safe.