Yes, you could "cure" and "cycle" the rock in your tank. But, the curing process if there happens to be any biological stuff on the rock can be very messy/smelly and require large water changes. If the rock is extremely clean, then you can just spray it off with a hose, let it air dry in the sun a couple of days, then use in your tank.
But, I think I would do a quick cure of the rock in a separate bin with a heater and powerhead. You can do this for a couple of weeks just to see if any "dirt" comes off the rocks in the form of organic matter breaking down. Check the water regularly for ammonia...if you are getting a large amount of ammonia off the rocks, then there was a lot of organics in the rock to break down. Doing it in a small bin allows you to do 100% water changes every couple of days until you don't see any further ammonia present....then your rock is cured.
Then, you can cycle the rock in the main tank with saltwater, bacterial starting agents, etc...