Here's what the AVMA guidance says about MS-222
Whereas the blunt force trauma + exsanguination method involves the following:
After that, it's just a matter of sliding a knife behind the gill plate and wiggling it around a bit. The fish will then bleed out and die. This is the same method used every day by anglers the world over to euthanize their catch. That's how I learned to do it -- fishing, as a child. It's quick and easy, like humane euthanasia should be.
There are other non-chemical options, but decapitation requires pithing (spike through the brain -- harder to locate exact impact point for the novice), cervical transection (severed spinal cord, but that also then requires pithing), maceration (quickly chopping up, probably the easiest method for small fish under 2" or so and those with suitable home appliances)
MS-222 might be the "cleaner" option, but it seems like it's both harder to procure (compared to a blunt object and knife) and harder to properly administer unless one wants to just go all out and intentionally drastically overdose with the $40(ish) per gram MS-222.
On to specifically mentioned inhumane/unethical methods per the AVMA, we find some of the methods commonly discussed on message boards.
These are the methods that there should be no tolerance of. Not the methods that
feel "icky" or "cruel." Let's allow the medicine/science lead here.
Overall, I think we, as a community, need to develop a standard when it comes to fish euthanasia. One that's easy to perform, not cost or material prohibitive, and one that aligns with AVMA guidance. I'm hardly an expert, but the document that
@Jay Hemdal provided earlier today offers some good places to start.