@Ach
Welcome.
I agree with the above. Honestly the tang will be ok for a short amount of time but it will outgrow the tank very quickly. As it does it will likely be more aggressive to everything else. Also as a newbie, I’m guessing you’ve yet to run into fish disease but smooth skin tangs like the hippo are ich magnets.
You either need two clowns or many clowns in any tank. One will likely be an outcast and killed.
As for the star fish… no one honestly knows what they eat. But unless you have an established aquarium it will likely starve. Even a sand sifter. Serpent stars however may work, as they eat detritus and even fish food like mysis or brine.
the tank should not be toxic at the bottom with flow and filtration. My guess is more towards parameters of the water chemistry, food, temp, or aggression from tank mates