check out this calculator from Tropic Marin,
ALL-FOR-REEF is an easy- to-use, highly concentrated solution for the supply of ALL essential minerals and trace elements in reef aquariums.
www.tropic-marin-smartinfo.com
It tells you how much calcium (mg/L) and dkH the recommended dosage provides to your tank daily.
For a 50 gallon system, they say ~9ml provides 2ppm Calcium and about 0.28 alkalinity.
So your 20mL dose would give about 4ppm and 0.56 dkH.
I think they base the recommended maximum dose on preventing the alkalinity from increasing more than 1dkH per day. But since All for Reef doesn't provide alkalinity the same way as other sources, ie it takes time for the calcium formate to process into alkalinity, there are people dosing higher levels than the recommended maximum.
I measured my alk today at about 7 dKH, this is after several days of dosing carbo calcium at just under the maximum dosage.