I would maybe try and get the Kamoer Stepper Doser since you can do a continuous mode, and you can adjust it up to 0.1 ml a minute. I have a 50 gallon so I need something to dose very slow, and it's continuous which is nice. If it gets unplugged and plugged back in it'll go back to the same continuous setting like nothing happened, so you may be able to use that to your advantage if using a probe along with it and having it work along with your pH levels.
Also the only other thing I can think of is a refugium to help pH, but I know not everyone has the space for that in the sump (I don't).
Maybe try microbubble scrubbing? Might help a tad, all you need is a air pump/stone.
I know it helps clear up organics in and around the rock which can clear out stuff and improve pH.
Also if you have liverock or some sort of hitchikers, something could have died and released a bunch of stuff that really is taking a toll on the pH. But this situation is strange and I hope it gets solved.
I had dealt with Pathogenic Bacteria with my corals for over a year and it was so upsetting and made me want to quit. I lost all so many of my stony corals despite my tank being great parameter/pest wise.