Hmm.. Lot's of answers to that question but the right answer is based on your set up, ca/alk demand, intent for dosing the kalk (I"m assuming to maintain a higher pH), current freshwater top off method, etc....
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The most common method of kalk dosing is to mix in a specific amount into your freshwater top off and dose it over a period of time (ideally 24/7 but many dose kalk overnight since pH values are ususally lowest at night). Keep in mind that kalk is at max concentration when you mix 2 teaspoons per gallon of water (the concentration can be increased by adding vinegar to the solution but that's not a good practice to start out with). Kalk can be mixed as lightly as you want but the potency of the solution is maxed out at 2 tsp/gallon. In order to help you determine the best starting dose we would need to know your current alk/ca supplementation methods and dosing amounts. If your just starting a ca/alk supplementation regimen then I would suggest the following:
1) calculate your total 24 hour evaporation amount (how much fresh water do you add daily to maintain salinity at a stable reading).
2) mix a solution of kalk starting with a ratio of 1/4th teaspoon (not tablespoon) per gallon of water.
3) Use your kalk solution in replacement for your daily fresh water top off.
4) Don't dose it all at once!!! Dose it over at least 12 hours and ideally over 24 hrs. Dosing it all at once will likely cause a major precipitation event and spike your pH high enough to kill most living animals in your tank.
5) Monitor your alk level daily. Daily monitoring as your getting a concentration dialed in is vital. It can save you lots of headaches as well as helping to prevent major shifts in alk levels. If after a few days you notice your alk is slowly dropping then increase the concentration of the kalk solution. If your alk is slowly raising then slightly decrease the kalk concentration. Knowing your current method of supplementation and daily alk uptake will help us guide you to a proper starting dosing regimen that will help prevent any quick changes in alk. Fast changes in alk is often detrimental to stony corals. If your starting with your ca at an acceptable range then there is really no need to monitor ca as frequently as alk (if your using kalk as your sole means of ca/alk supplementation). Kalk replenishes ca and alk at the same ratio that reef inhabitants utilize it. Generally if alk moves 1dkh up or down then ca will follow it up or down by a value of approx 20 ppm. If your alk is kept steady at a certain value, and kalk is the only means of ca/alk supplementation, then your ca will stay steady as well (there are a few odd scenarios that can cause an imbalance in ca and alk when dosing kalk but they are very rare occurrences and very unlikely to be an issue for you). I personally do check ca once a month just to be sure everything is still in line.
Since I don't know your method of top off, tank volume, current method of ca/alk supplementation, or the daily alk consumption rate I can't give much more advice than that for now.
Jeremy