You can use muriatic acid or certain freshwater buffers to lower alk.
Both will lower pH similarly and a lot. There's no way around the pH lowering when reducing alkalinity. You do not want to add CO2. You want to remove CO2 from the tank via aeration.
For that reason, it is best to do it in water change water that is aerated to raise pH before using, or to do it very slowly in the tank (over many days).
The "acidity" (that being essentially negative alkalinity) of muriatic acid straight from the bottle is about 11,000 meq/L.
So adding 1/11,000 of the water volume as this acid will drop alkalinity by 1 meq/l (2.8 dKH).
I would not drop more than 1 dKH per day due to the big pH drop in a reef tank, but in new salt water it is fine.
You'll need to aerate well after adding the acid to blow off the excess CO2 and bring up the pH.
You can also use Seachem Acid Buffer:
http://www.seachem.com/Products/product_pages/AcidBuffer.html