What should I do to raise and maintain my alk? Will just adding kalkwaser in my ATO raise it?
Kalkwasser is a good way to maintain levels of calcium and alkalinity in equal proportion. You would need to get your alkalinity up via another additive for alkalinity before you start dosing kalkwasser.
Kalk is more of a maintain the levels more than just raising one at a time.
In my experience trying to raise alk with kalk dosing doesn't work all that well, and additional supplement like seachem or BRS 2 part was needed to get the value up.
Water changes won't maintain the levels unless you change a massive amount of water at one time, so for example 50 gallon system with a dkh of 6.7 and after a 10 gallon water Change with dkh of 9 won't really have any affect on raising the tanks dkh. A 30 or 40 gallon water change would have a better chance at raising the alk but I don't recommend it.
When you mix your water you want to match the salinity of your display tank. Along with salinity you also want to match the temperature so you don't shock fish or corals, nor do you want to add hot water.
Alkalinity is also important to match in your fresh made seawater before you add it to the tank because a fluctuating alkalinity is not good for corals. So if your alk is 6.7dkh in the tank and your mixed water has an alk of 9 dkh then you will have pockets of water with a higher alk that can burn corals or stress them.
So after the long winded version

I would recommend you buy a type of supplement to dose your alkalinity up slowly ( not more than 1 dkh a day)
Raise it to match the dkh of your salt mix to make things easier on you and safer or less stressful for your reef.
You could use mrs. Wages picking lime for your kalkwasser dosing in your top off water. This is a inexpensive product that works well and you could make a drip system out of a container and some air line tubing with a 1/4 valve to adjust drip rate. This way you could skip the auto top off dosing and drip dose the tank at night to keep the parameters dialed in and constant.
Hope this helps you and others as well
Good luck and happy reefing
BluewaterLa/ Mike