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Do not add pre mixed salt water to top off your tank! You should be using fresh RO/DI water to top off the tank. When water evaporates from the tank, the salt does not leave the system so as more water leaves the tank via evaporation, the salt content, or salinity will rise slightly. If you topped off with mixed salt water, over time your salinity will rise to deadly levels. You want to try and maintain your water patrameters like salinity and keep them as constant as possible. Avoid letting that much water evaporate before topping off to avoid big swings in salinity and temperature. Add fresh water slowly to avoid shocking any live stock. You look to be about 4-6 gallons low, so add that much of 15-20 minutes, allowing time for it to mix before the next addition.
Adding pre mixed saltwater or fresh RO/DI water would depend on how much water you are adding to how large/small a tank.
This tank looks to be a small one. If you were to add 4 to 6 gallons of RO/DI water as you suggest there is a pretty good chance that the salinity level would drop.
Most people, know to check their salinity level before adding any kind of water more than a gallon or so.

