50 lbs of live rock is a little low for a 165gal system. I have found that SPS need lots of biodiversity with pods, mircofauna, etc. All mine died until I created a) a very stable system with no alk swings and b) a very biodiverse environment.
There is a youtube video of Mike Paletta talking about setting up a new system with new rock and everything he put in there (mostly SPS) died for about a year until he finally added live rock from a older system to help with the microfauna, etc and then everything was fine.
other than that, i've also come to the conclusion that some corals just die. No need to tweak the tank constantly because one coral isn't doing well.