Interesting observations there. Not sure that the red light had any effect whatsoever on the bleaching you observed -I would surmise it was the overall quantity of light that accelerated the bleaching in the sunlit portion compared to the more weakly illuminated LED side. The best analogy I can think of to what likely occurred is if you took a car engine and filled it full of gas but let all the coolant drain out of the system. Imagine revving it to max rpm and running it til it blew up. It would happen significantly faster than if you let the car idle with the same imminent overheating result. The light exposure is like a foot on the throttle. With less light intensity the inevitable bleaching due to phosphate starvation would have occurred much slower in the LED side. Makes perfect sense the sunlit side bleached out faster. Glad to hear you were able to ID the problem and correct course.I've got a pocillopora coral in my tank that due to shading from rock of the sunlight that comes in through the back window, only the half of the colony close to the front glass gets sunlight, the back half only gets my weak mostly blue LEDs.
The sunlit half has now grown much faster, and is significantly taller then the back half. The sunlit half, however is brown and the back half has better fluorescence. That is as expected.
A while back the colony bleached - I let phosphate go to zero while nitrates were elevated, full recovery was made with dosing phosphate. Rather I should say part of the colony was bleached, I just went back and pulled up the pictures....
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... it of course is the sunlit part that bleached, and there was no bleaching in the back half (far right in pic) that receives no sunlight, only much less light from blue heavy LED.



