So, regarding the low pH of the tank, I think I made progress. In order to explain, I have to tell some history.
Originally, years ago, my tank had a skimmer, and a plumbed-in frag tank. At some point, I took out the skimmer because I was constantly running low on nutrients. At the time, I watched for any impact on the PH but there was none.
A few months ago, I received a frag with a nuisance turf algae, and it took over my frag tank. I disconnected the frag tank from the main system, and have been trying several methods of trying to kill the algae, all with no success. Ultimately, I've been giving most of my energy to manual removal, and spot treating with hydrogen peroxide.
I didn't notice this issue in the main tank at that time, but I'm now suspecting that the frag tank aeration supplemented what I lost when I removed the skimmer - but all along I've needed at least one of the two. Based on the comments about increasing the gas exchange, I decided to reconnect the frag tank to see if it had in fact played an unexpected role in this situation, and it definitely appears to be making a difference.
You can see the sharp increases on the left from when I was dosing before reaching my alkalinity of 11, and you can see the low average in the middle after the initial dosing effect wore off. Then you can see the gradual increase on the right from 12 hours ago when I reconnected the frag tank. No other changes were made that would impact the PH (no dosing, no water changes, etc.). It appears to be holding steady around 8, and it so far doesn't appear to be swinging as far either, which is a huge improvement.
Any additional thoughts are welcome. For now I'm just going to give it a few days and watch the levels.
P.S. Please don't give me grief on the spikes, the area I dose at is directly next to the probe in my sump.