I used ATO based Kalkwasser dosing for years. Switched to a measured dose from a dosing pump a year ago. Love it. Most stable Calc/Alk I've _ever_ had in one of my tanks. I'm still using ESV B-Ionic Calc/Alk and Mag, the Kalkwasser just lets me reduce the quantity. Substantially. My pH varies from 8.0 to 8.3 daily.
A few points: Kalkwasser must be made with fresh water. Preferably, RO/DI. You can't make it with salt. So... it's not going to raise your sodium, like your red sea Calc/Alk does. It's a very natural, balanced method of maintaining Calc/Alk, as long as your tank usage doesn't outstrip what Kalk is capable of. You can only put as much Kalk in as your system evaporates. That's why ATO kalk systems are so common.
Dosing outside of the ATO: Pick a starting point. Something _less_ than what your ATO uses in a day, and dose that amount of Kalk. On my 140g system, I started with 250ml per day. Watch your Calc/Alk closely, and see if you need to reduce (or even eliminate) your red sea Calk/Alk dosing. At this point, I'm dosing 1000ML Kalk daily, and have reduced my B-Ionic Calc and Alk dosing by half. I mix up a 2g container of Kalk every other week, and I'm good.
Oh, what Sabellafella said about Kalk crusting up pipes is correct. I drop my Kalk dosing pickup tube into the sump while I'm waiting for the Kalk to settle. Let the pump run a few ounces of clean saltwater through it. It's enough to keep the tubes clear.