Good question.
The premise of mixing vodka and vinegar is to avoid a “monoculture” of bacteria. Carbon dosing, especially vinegar, can spur a wide variety of organisms. I have also seen great tanks with vodka dosing.
I believe that fear is not warranted, but you can mix them both if you want to. I will consider making a new graph for those who want to use both.
Corals, sponges, and filter feeders can directly consume the acetate in vinegar for energy. They can use acetate as a building block to make fatty acids, too.
Vinegar is one of the most highly processed organic in the ocean; dosing vinegar can be very natural to the organisms in our tank.
A few potential downsides to vinegar:
1) May increase zooxanthella (darker corals)
2) May increase pest organisms like aiptasia, vermitids, and dinoflagellates, especially with higher doses.
3) Lower pH spikes when not using a doser.
The downsides 1 & 2 won’t happen in every tank. It’s only theoretical. If you aren’t getting cyano with vodka, there’s no reason to switch it. I like vodka as a carbon source. Both work equally well for NO3 when using the charts I made.